How can I tell if he's flirting with her? Advice?

Me and my boyfriend broke up for a week a while ago because he went out with a girl (as friends apparently) that I wasn't entirely secure on him being with alone, so I told him then he broke up with me saying I was to insecure. We've been back together for 6 months and fully for almost 2 years. 
​He's invited her on one of our days out soon and I didn't really want to go but now I think it might be useful so I can see if I was right in thinkin he has a thing for her so I've decided not to cancel so I can do some research basically. 
​I know a couple of things about flirting but I want to know all of the signs so I can assess weather there could be a thing between them or not.. I know it sounds crazy but I suppose I just can't get rid of this gut feeling. 
​Any chance I can get some tips as to what to look out for?? This is the make or break of our relationship so I need to get it right.