plan B?

So me and my boyfriend had sex yesterday night and he didn't pull out (no condom/ birth control). On certain days I tell him it's fine (he's done it twice before and everything was fine) but yesterday I didn't. Every single time it was fine my fertile window was at 7%. Yesterday's was 11%, I'm wondering if I should be fine or..? He's offering to purchase plan b and I'm not sure what to do.