Meeting his wife

So I have a good friend at work who happens to be a male... He's married, I'm married. We both respect that and each other. He's moving out of his apartment and they're moving into a house this weekend. My husband and I are helping them out since they need a hand and I offered. It'd be our first time hanging out of work and meeting our partners... If given the chance, should I talk with his wife about her husband and I? Like the fact that she doesn't have to worry about me making a move or something... I'm not sure if I'm making sense. I guess being a woman... I'd be a little iffy about my husband having a female friend at times .. not that I'm jealous or anything, I'm just an overthinker is all...