Does anyone ovulate while on af?

My husband and I have been ttc #1 for several months with no luck. We try to remember that everything happens in due time but do the best we can at the same time. This might be tmi but I'm on day 2 of af and all day after the restroom I noticed, aside from the obvious af, it was kind of clear, snot looking. I've only ever noticed this consistency while on af. So I'm thinking I ovulate on my period. Anyone else? Do ovulation kits work while on af? Thanks in advance.