Can you get pregnant if you’re not ovulating?

Not trying to conceive, as I am young and not looking to start a family yet. However I am on accutane and have to use 2 forms of birth control. My s/o and I are starting to use condoms on top of the pill, but find it just uncomfortable for the both of us.

My question is, if we have sex NOT during the times I am ovulating, is it okay if he just pulls out??

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