Taking estrogen after ovulation?

My OB prescription estrogen for me to take after the trigger shot because my lining was only 5mm has anyone else took estrogen after ovulation? I thought you had to take it before ovulation for it to be effective

Also I was only on cd 11 with a 17mm follicle I’m on day 13 now and taking the trigger tonight is there any chance my lining is thicker now?

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