How and when to start pumping

Al
So my daughter is almost 2 weeks old and is a breastfeeding champ! She latched within 20 min of being born and hasn't looked back. She eats every 2 hours on the nose and recently has been falling asleep in between sides. it takes some effort to arouse her for the other. So by the time she's done I only have an hour break in between nursing sessions.  It feels like alllll I do is nurse !! (I know it's only temporary but I have had zero sleep in two weeks 😰)
I'd like to start introducing a bottle with pumped milk once or twice a day. That way dad can help and bond. it will also get both of us ready for when I return to work in 10 weeks! 
So how do I do this! She eats so frequently I don't see how I could add a feeding in to start a pumping schedule ? Help! 

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