How to pump for one feed?

Hi👋🏻 FTM here. I want to switch one of my nursing sessions to a pumping session so I can use that to start a stash for daycare and get her used to a bottle. I get enough during the night use the haakaa to replace the feed so whatever I pump would be for the freezer.

My question is which feed would be the best to replace? The morning, an evening or night time feed?

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