When can I freeze milk

Livia

I have pumped 4oz milk and kept it at room temperature at 7 am. At 9:30 am my son drank 2 oz milk and slept. It has been 11:30am and he did not wake up. Can I freeze that other 2 oz milk at 11:30 am ( it has been 4 hrs from the time I pumped. I know we can go till 6 hrs if needed, but in the meanwhile I pumped again and I want to freeze the previous milk

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